This recommendation was raised in the review of the Poseidon paper.
The BioSamples database (https://www.ebi.ac.uk/biosamples/) is an attempt to provide universal sample IDs across the life sciences and is used by the archives for sequence reads (ENA/SRA/DDBJ). Essentially every published ancient sample already has a BioSample accession, because this is required for the submission of sequence reads to ENA/SRA/DDBJ. It would thus have seemed natural to make BioSamples IDs a central component of Poseidon metadata, so as to anchor Poseidon to the mainstream infrastructure, but this is not really done. There are some links being made to ENA in the .ssf "sequence source" files used by the Poseidon package, including sample accessions, but this seems more ad-hoc.